Synthesis and Crystal Structure of Barium Indide Ba9In4

نویسندگان

Volodymyr Smetana

Arndt Simon

چکیده

A new binary compound in the system Ba-In has been synthesized and structurally characterized. According to singlecrystal X-ray diffraction data Ba9In4 crystallizes with tetragonal symmetry (I4/m, a = 13.948(2), c = 5.888(1) Å, V = 1145.5(3) Å3, Z = 2, R1 = 0.037, wR2 = 0.071). The very moisture-sensitive compound could be obtained as single phase by reaction of metallic barium and indium at 350 ◦C.

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